Not doubting, but I'd like to know if there are examples of where people raised the pH of the soil without any additives except plants.
Plants and organic matter lower soil PH, not raise it. Liming is the only practical way to raise soil PH. There's no reason to be scared of liming soil, it's not a poisonous chemical, it's only ground powdered rock. The following primer off of Wikipedia spells out what determines soil PH;
Factors affecting soil pH
The pH of a natural soil depends on the mineral composition of the
parent material of the soil, and the weathering reactions undergone by that parent material. In warm, humid environments,
soil acidification occurs over time as the products of
weathering are leached by water moving laterally or downwards through the soil. In dry climates, however, soil weathering and leaching are less intense and soil pH is often neutral or alkaline.
Sources of acidity
Many processes contribute to soil acidification. These include:
- Rainfall: Acid soils are most often found in areas of high rainfall. Rainwater has a slightly acidic pH (usually about 5.7) due to a reaction with CO2 in the atmosphere that forms carbonic acid. When this water flows through soil it results in the leaching of basic cations from the soil as bicarbonates; this increases the percentage of Al3+ and H+ relative to other cations.
- Root respiration and decomposition of organic matter by microorganisms releases CO2 which increases the carbonic acid (H2CO3) concentration and subsequent leaching.
- Plant growth: Plants take up nutrients in the form of ions (e.g. NO−3, NH+4, Ca2+, H2PO−4), and they often take up more cations than anions. However plants must maintain a neutral charge in their roots. In order to compensate for the extra positive charge, they will release H+ ions from the root. Some plants also exude organic acids into the soil to acidify the zone around their roots to help solubilize metal nutrients that are insoluble at neutral pH, such as iron (Fe).
- Fertilizer use: Ammonium (NH+4) fertilizers react in the soil by the process of nitrification to form nitrate (NO−3), and in the process release H+ ions.
- Acid rain: The burning of fossil fuels releases oxides of sulfur and nitrogen into the atmosphere. These react with water in the atmosphere to form sulfuric and nitric acid in rain.
- Oxidative weathering: Oxidation of some primary minerals, especially sulfides and those containing Fe2+, generate acidity. This process is often accelerated by human activity:
- Mine spoil: Severely acidic conditions can form in soils near some mine spoils due to the oxidation of pyrite.
- Acid sulfate soils formed naturally in waterlogged coastal and estuarine environments can become highly acidic when drained or excavated.
Sources of alkalinity
Total soil alkalinity increases with:
- Weathering of silicate, aluminosilicate and carbonate minerals containing Na+, Ca2+, Mg2+ and K+;
- Addition of silicate, aluminosilicate and carbonate minerals to soils; this may happen by deposition of material eroded elsewhere by wind or water, or by mixing of the soil with less weathered material (such as the addition of limestone to acid soils);
- Addition of water containing dissolved bicarbonates (as occurs when irrigating with high-bicarbonate waters).
- The accumulation of alkalinity in a soil (as carbonates and bicarbonates of Na, K, Ca and Mg) occurs when there is insufficient water flowing through the soils to leach soluble salts. This may be due to arid conditions, or poor internal soil drainage; in these situations most of the water that enters the soil is transpired (taken up by plants) or evaporates, rather than flowing through the soil.
The soil pH usually increases when the total
alkalinity increases, but the balance of the added cations also has a marked effect on the soil pH. For example, increasing the amount of sodium in an alkaline soil tends to induce dissolution of
calcium carbonate, which increases the pH.
Calcareous soils may vary in pH from 7.0 to 9.5, depending on the degree to which Ca2+ or Na+ dominate the soluble cations.