Yes, dunking them is fine. I used to use large tubs to soak 3 gal RMs. I would not soak 18s.
Also, keep in mind, if you are using the right kind of chunky mix it should have lots of voids in it. When you first transplant, water should run through it like a sieve. As the roots continue branching they fill those voids making them harder to top water. When they become difficult to water and you need to dunk them, you are likely better off transplanting to the next larger container if possible.
One last caution. If you have any kind of disease with any of the trees, dunking them in the same tub of water can transmit the disease depending on what it is. I have not had that happen, but it can.
Since you said you just did the transplant, I would reconsider the mix you are using. I like to add pine bark nuggets to promix to make it even chunkier. They should not be hard to water when first transplanted.