Here is some information on thistles that might interest you.
The common Canada Thistle isn't originally from Canada. It was probably introduced to the US from Canada, but it's not native to Canada and was introduced there from Eurasia.
The Bull Thistle is also an introduced species and looks a lot like the native Pasture Thistle. However, the easy way to tell those two apart is that the underside of the native leaves almost look white. The leaves of the Bull Thistle don't look like that. Some environmentalist rave about how we should save the native thistles. I guess they have their place, but I just don't care for thistles. I spray all of them when I see them. There are many native thistles besides the Pasture Thistle, but it is about the only one I see in my NWSGs. I went to war against the Musk Thistle many years ago, and have come very close to eliminating them. I only found 2 on 100 acres this year.
BTW - the native pasture thistle is a hard one for me to see in my NWSGs because of how the color blends in and how late it starts growing. It also flowers very late. My NWSGs will be at full height before it flowers, and you can hardly see the darn things. At least the hated Musk Thistle that we all try to eradicate blooms early and sticks out like a sore thumb with those bright red blooms.
Below are some pictures of the native Pasture Thistle (Cirsium discolor) that I took recently. If you have this one, at least it is native and some environmentalist want them there - but as I said, I still kill them when I see them. I figure that even with me killing them, there will be enough left for the thistle huggers.....
Don't let the short height of the one in the picture fool you. I killed some of those the other day that were 9 feet tall. The pic of the leaf underside illustrates what I was talking about with the white color.
PS - to answer the original question - I find that Crossbow smokes them. I like spraying them with this in the NWSGs because it doesn't hurt the grass. A good strong does of 24D would likely be just as good. Sometimes if I can get to them easy, I cut them off with a shovel and gly treat the stump. That works too.